WebApr 3, 2024 · Figure 1. Typical flow curve of polymer melts. Image Credit: Dynisco. The flow curve of polymer melts is bound by two limiting slopes (dashed lines) which determine the zero-shear viscosity value (n 00 and the Power-law index value (n)), as shown in Figure 1.These parameters can be used to estimate molecular weight (M w) as well as the … WebSep 19, 2003 · The flow of polymers, either as melts or in solution, shows some intriguing features. Polymeric liquids climb stirrer rods (the Weissenberg effect), swell up at the exit of an extruder or capillary, and can even sustain tubeless siphons (1, 2). These phenomena cannot be explained by classical hydrodynamics. Yet they are typical of most polymeric …
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WebA tiny amount of long-chain flexible polymer dissolved in a fluid can drastically change the flow properties. At low Reynolds numbers, a normal fluid flow is stable and laminar, while the addition of polymers can induce strong fluctuations and create elastic turbulence ().In high–Reynolds number turbulent flows, polymer additives modify the momentum and … WebSep 12, 2024 · In polymer chemistry, the width of the distribution of molecular weights is described by the dispersity (Ð, also called, in older texts, the polydispersity or the polydispersity index, PDI). The dispersity of a polymer sample if often between 1 and 2 (although it can be even higher than 2). The closer it is to 1, the narrower the distribution. WebSep 12, 2024 · In this case, the relationship is described by the Mark-Houwink equation: (4.2.1) [ η] = K M α. In this equation, [η] is the intrinsic viscosity; that's the viscosity attributed to the solute, rather than the viscosity of the solvent itself. M is the molecular weight. K and α are constants for a particular polymer. brother printer jams when printing two sided